나이트로 화합물의 알칼리성 Sodiumborohydride에 依한 二液相還元에 關한 硏究
Study on two phase reduction of Nitrocompounds with alkaline aqueous sodiumborohydride
광주보건전문대학논문집 1975년 2권 1호 p.94 ~ 99
함희석,
소속 상세정보
함희석 ( Ham Hee Suk )
광주서원전문학교 영양과
KMID : 0615219750020010094
Abstract
TWO phase reduction of representative nitrocompounds with alkaline stabilized Sodium borohydride solution was examined. Chloronitrobenzene and nitrotoluene were not reduced, but nitrophenol (0-, m-, p-) and Dinitrobenzene (0-, m-, p-), 2.4-dinitrochlorobenzene were reduced. As a result, when electron releasing power was smaller and electron attracting power was larger, these compounds were reduced.
On nitrogroup was, however, reduced 25% in 12hr and 58% in 24hr. and nitrophenol were reduced 25% in 24hr. When two nitrogroup of dinitrobenzene (0-, m-, p-) and 2. Cdinitrobenzen were reduced, they were reduced 30% in 24hr.
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