Development of fluorination methodology for carbon-fluorine bond formation: old electrophilic fluorinating reagents
Bae Dae-Young, 이은성,
소속 상세정보
( Bae Dae-Young )
Pohang University of Science and Technology Department of Chemistry
이은성 ( Lee Eun-Sung )
Pohang University of Science and Technology Department of Chemistry
Abstract
Electrophilic fluorinating reagents are typically efficient for carbon?fluorine (C?F) bonds formation due to their higher reactivity even under mild condition. Thus, they have been playing an important role to improve C?F bonds formation reactions via direct fluorination reaction with electrophilic fluorinating reagents or transition metal catalysis. Advances on the recent fluorination methods are mainly results of SelectfluorTM’s capability on facile fluorination. In this mini-review, we describe synthesis and application of four old yet popular electrophilic fluorinating reagents such as N-fluorobenzenesulfonimide (NFSI), N-fluoropyridinium salts, SelectfluorTM, and N-fluorosultam.
키워드
Fluorination; Carbon-fluorine bond; Electrophilic fluorinating reagents; Catalysis
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