피리딘-테트라히드로푸란 용매중에서 수소화붕소 나트륨에 의한 몇 가지 작용기를 갖는 유기화합물들의 환원반응
Reduction of Organic Compounds Containing Some Functional Groups with Sodium Borohydride in Pyridine Tetrahydrofuran Solvent
광주보건전문대학논문집 1976년 3권 1호 p.45 ~ 49
소속 상세정보
咸喜錫
KMID : 0615219760030010045
Abstract
The reduction of aliphatic and aromatic alcohols, aldehydes, ketones, styrene and ca rboxylic acids were examined with sodium borohydride in 2:1 pyridine-tetrabydrofuran Octyl alcohol and. phenol were consumed 1 eguivalent of hydride for hydrogen evolution in 24 hr. and 3 br. ,and butyraldehyde, benzaldehyde, cyclohexanone, :benzophenon e, acetophenone, 2-heptanone and styrene were consumed 1 equivalent of hydride for reluction without evolution of hydrogen´. Ethylacetate and ethylbenzoate were consumed 2 equivalents. Caproic acid and benzoic acid were requirei4 equivalents ,of .hydride, 1 equivalent for hydrogen evolution and 3 for reduction.
키워드
원문 및 링크아웃 정보
등재저널 정보